Detailed Product Description:
One of the alkali metals, potassium is one of the lowest density metals,
second only to lithium. It is a soft, low-melting point solid that can
easily be cut with a knife. Freshly cut potassium is silvery in appearance,
but in air it begins to tarnish toward gray immediately. Potassium and
its compounds emit a violet color in a flame. This fact is the basis of
the flame test for the presence of potassium in a sample.
Chemical Properties
Potassium must be protected from air for storage to prevent disintegration
of the metal from oxide and hydroxide corrosion. Like the other alkali
metals, potassium reacts violently with water producing hydrogen. The
reaction is notably more violent than that of lithium or sodium with water,
and is sufficiently exothermic that the evolved hydrogen gas ignites.
Potassium compounds generally have excellent water solubility, due to
the high hydration energy of the K+ ion. The potassium ion is colorless
in water.
Applications:
Because potassium reacts quickly with even traces of water, and its
reaction products are nonvolatile, it is sometimes used alone, or as NaK
(an alloy with sodium that is liquid at room temperature) to dry solvents
prior to distillation. In this role, it serves as a potent desiccant.
Precautions
Solid potassium reacts violently with water, and should therefore be kept
under a mineral oil such as kerosene and handled with care. Unlike lithium
and sodium, however, potassium cannot be stored under oil indefinitely. If
stored longer than 6 months to a year, dangerous shock-sensitive peroxides
can form on the metal and under the lid of the container, which can detonate
upon opening. It is recommended that potassium metal not be stored for
longer than three months unless stored in an inert (oxygen free) atmosphere,
or under vacuum.
The extremely alkaline potassium hydroxide (KOH) residue on the surface
of potassium which has been exposed to moisture, is a caustic hazard. As
with sodium metal, the "soapy" feel of potassium metal on skin is due to
caustic breakdown of the fats in skin into crude soft potassium soap, and
represents the beginning of an alkali burn. Potassium should obviously be
handled with care, with full skin and eye protection.
Potassium fires are exacerbated by water, and only a few dry chemicals
are effective for them. Potassium also reacts violently with iodine.
Must be stored in airtight containers or in kerosene, mineral oil, or
similar liquid that does not contain water or free oxygen.
Download MSDS, read and understand fully, the dangers and precautions
associated with the use of this substance.
Click here to download MSDS (Material Safety Data Sheet)
Packaging:
Contains 25 grams potassium cubes packed in mineral oil in 250ml
wide-mouth jar.
Availability:
This material is available by special order only. Please allow 2-3 weeks
after receipt of order.